OSHA's Hazard
Communication Standard (HCS) specifies certain information that must
be included on MSDS, but does not require that any particular format be
followed in presenting this information. In order to promote consistent
presentation of information, OSHA recommends that MSDS follow the
16-section format established by the American National Standards Institute
(ANSI) standard for preparation of MSDS.
By following this
recommended format, the information of greatest concern to workers
is featured at the beginning of the data sheet, including information on
chemical composition and first aid measures. More technical
information that addresses topics such as the physical and chemical
properties of the material and toxicological data appears later in the
document. While some of this information (such as ecological information)
is not required by the HCS, the 16-section MSDS is becoming the international
norm. The 16 sections are:
- Identification
- Hazard(s) identification
- Composition/information on ingredients
- First-aid measures
- Fire-fighting measures
- Accidental release measures
- Handling and storage
- Exposure controls/personal protection
- Physical and chemical properties
- Stability and re-activity
- Toxicological information
- Ecological information
- Disposal considerations
- Transport information
- Regulatory information
- Other information
Section 1: Chemical Product and Company Identification
This section links
the chemical name on the label to the MSDS. The MSDS also
lists the name, address and the phone number of the company, manufacturer or
distributor
who provides the
chemical.
Section 2: Composition, Information or Ingredients
This section must
identify all the hazardous ingredients of the material. This
section may also include OSHA Permissible Exposure Limits (PELs), Threshold
Limit Values (TLV), etc.
Section 3: Hazard Identification
This section
discusses the health effects one may encounter when
exposed to the material. The section will describe the
appearance of the material, the potential health effects and symptoms
associated with exposure, routes
of entry, target organs that could be affected, and so on.
Section 4: First Aid Measures
This section will
describe possible first aid procedures for each route of entry.
The procedures will be written so that untrained individuals
can understand the information.
Section 5: Fire-Fighting Measures
This section will
describe information on the fire and explosive properties
of the material, extinguishing items, and general
fire-fighting instructions.
Section 6: Accidental Release Measures
This section gives
information on how to respond when a material spills,
leaks or is released into the air. This information may
include how to contain a spill or the types of equipment that may be
needed for protection.
Section 7: Handling and Storage
This section
discusses information on handling and storage of the material.
Topics that could be described are: general warnings to prevent
overexposure, handling procedures, and hygiene
instructions to prevent continued exposure.
Section 8: Exposure Controls and Personal Protection
This section
discusses engineering controls and personal protective equipment
that would help reduce exposure to the material. The
necessary personal protective equipment should be considered
for eye/face protection, skin protection and respiratory protection.
Section 9: Physical and Chemical Properties
This section will
include information about the physical and chemical
properties of the material. The following characteristics
should be detailed: appearance, odor, physical state, pH, vapor
pressure, vapor density, boiling point, freezing/melting
point, solubility in water and specific gravity or density.
Indicate if these characteristics do not apply to your
material.
Section 10: Stability and Reactivity
This section requires
that potentially hazardous chemical reactions be
identified. It addresses chemical stability, conditions to avoid,
incompatibility with other materials, hazardous
decomposition and hazardous polymerization.
Section 11: Toxicological Information
This section
discusses data used to determine the hazards that are given in
Section 3, “Hazard Identification.” The following information
can be addressed: acute data, carcinogenicity, reproductive effects,
target organ effects, etc.
Section 12: Ecological Information
This section will
help determine the environmental impact should the
material ever be released into the environment.
Section 13: Disposal Considerations
This section gives
important information that may be helpful in the proper
disposal of the material. The information can cover disposal,
recycling and reclamation.
Section 14: Transport Information
This section is
designed to give basic shipping information. The basic shipping
information could include: the hazardous materials
description, hazard class and the identification number (UN or NA
numbers).
Section 15: Regulatory Information
This section
discusses information on the regulations under which the
material falls. Examples of a few regulatory agencies are: OSHA,
TSCA (Toxic Substance Control Act), CERCLA (Comprehensive Environmental Response,
Compensation, and Liability Act), SARA Title III (Superfund
Amendments and Reauthorization Act).
Section 16: Other Information
This section should
include any other important information concerning the
material. This information can include: hazard ratings, preparation and
revisions of the MSDS, and label information.
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